Hydrocarbon Uptake in the Alkylated Micropores of a Columnar Supramolecular Solid | Zendy

Taylor Thomas J. | Zendy; Bakhmutov Vladimir I. | Zendy; Gabbaï François P. | Zendy

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Hydrocarbon Uptake in the Alkylated Micropores of a Columnar Supramolecular Solid

Author(s) -

Taylor Thomas J.,

Bakhmutov Vladimir I.,

Gabbaï François P.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602440

Subject(s) - trimethylsilyl , adsorption , hexagonal crystal system , supramolecular chemistry , ionic bonding , chemical engineering , alkylation , chemistry , crystallography , materials science , organic chemistry , crystal structure , ion , engineering , catalysis

Neither Doric, Ionic, nor Corinthian! (HgC 6 F 4 ) 3 interacts with 1,3,5‐(Me 3 SiCC) 3 C 6 H 3 to form columns with peripheral trimethylsilyl groups. These columns self‐aggregate into a hexagonal solid containing pores lined by nonpolar methyl groups (see picture; Hg orange, Si purple, C gray, F green, H white), which can adsorb alkanes reversibly.

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