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Pd II ‐Catalyzed Aerobic Allylic Oxidative Carbocyclization of Allene‐Substituted Olefins: Immobilization of an Oxygen‐Activating Catalyst
Author(s) -
Piera Julio,
Närhi Katja,
Bäckvall JanE.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602421
Subject(s) - allylic rearrangement , catalysis , chemistry , allene , oxygen , oxidative phosphorylation , photochemistry , palladium , organic chemistry , biochemistry
A good couple : Highly selective aerobic allylic oxidation with CC bond formation is achieved by the use of coupled palladium and iron catalysis (see scheme; FePc=iron phthalocyanine). The use of an oxygen‐activating catalyst is necessary for an efficient electron transfer from Pd 0 to O 2 . The utility of this method is enhanced by the immobilization of the iron catalyst onto a resin.