Pd II ‐Catalyzed Aerobic Allylic Oxidative Carbocyclization of Allene‐Substituted Olefins: Immobilization of an Oxygen‐Activating Catalyst | Zendy

Piera Julio | Zendy; Närhi Katja | Zendy; Bäckvall JanE. | Zendy

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Pd II ‐Catalyzed Aerobic Allylic Oxidative Carbocyclization of Allene‐Substituted Olefins: Immobilization of an Oxygen‐Activating Catalyst

Author(s) -

Piera Julio,

Närhi Katja,

Bäckvall JanE.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602421

Subject(s) - allylic rearrangement , catalysis , chemistry , allene , oxygen , oxidative phosphorylation , photochemistry , palladium , organic chemistry , biochemistry

A good couple : Highly selective aerobic allylic oxidation with CC bond formation is achieved by the use of coupled palladium and iron catalysis (see scheme; FePc=iron phthalocyanine). The use of an oxygen‐activating catalyst is necessary for an efficient electron transfer from Pd 0 to O 2 . The utility of this method is enhanced by the immobilization of the iron catalyst onto a resin.

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