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Diastereoselective Gold‐Catalyzed Cycloisomerizations of Ene‐Ynamides
Author(s) -
Couty Sylvain,
Meyer Christophe,
Cossy Janine
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602270
Subject(s) - ene reaction , catalysis , chemistry , cycloisomerization , combinatorial chemistry , medicinal chemistry , organic chemistry
Around they go : 1,6‐Ene‐ynamides undergo highly diastereoselective gold‐catalyzed cycloisomerizations that lead to functionalized cyclobutanones or carbonyl compounds with a 2‐azabicyclo[3.1.0]hexane subunit, depending on the substitution pattern (Ts= p ‐toluenesulfonyl).
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