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Regioselective Iron‐Catalyzed Allylic Amination
Author(s) -
Plietker Bernd
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602261
Subject(s) - regioselectivity , allylic rearrangement , moiety , aniline , stereoselectivity , amination , catalysis , chemistry , substrate (aquarium) , combinatorial chemistry , organic chemistry , oceanography , geology
Iron age : An air‐ and water‐resistant iron(−II) catalyst, in the presence of triphenylphosphane under buffered conditions, allows for the highly regioselective and stereoselective allylation of primary aromatic amines. A broad substrate range both in the aniline and in the allyl carbonate moiety is tolerated.