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Anion‐Templated Syntheses of Pseudopeptidic Macrocycles
Author(s) -
Bru Miriam,
Alfonso Ignacio,
Burguete M. Isabel,
Luis Santiago V.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602206
Subject(s) - template , ion , scheme (mathematics) , chemistry , combinatorial chemistry , computer science , stereochemistry , nanotechnology , materials science , organic chemistry , mathematics , mathematical analysis
A very welcome guest : The terephthalate anion efficiently templates the selective assembly of a tetraimino dianion host–guest complex, which can be reduced to the final [2+2] pseudopeptidic macrocycle (see scheme; O red, blue N).
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