Cationic Terminal Borylene Complexes: Structure/Bonding Analysis and [4+1] Cycloaddition Reactivity of a BN Vinylidene Analogue | Zendy

Aldridge Simon | Zendy; Jones Cameron | Zendy; GansEichler Timo | Zendy; Stasch Andreas | Zendy; Kays née Coombs Deborah L. | Zendy; Coombs Natalie D. | Zendy; Willock David J. | Zendy

Premium

Cationic Terminal Borylene Complexes: Structure/Bonding Analysis and [4+1] Cycloaddition Reactivity of a BN Vinylidene Analogue

Author(s) -

Aldridge Simon,

Jones Cameron,

GansEichler Timo,

Stasch Andreas,

Kays née Coombs Deborah L.,

Coombs Natalie D.,

Willock David J.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602162

Subject(s) - cationic polymerization , delocalized electron , cycloaddition , chemistry , reactivity (psychology) , character (mathematics) , stereochemistry , crystallography , polymer chemistry , computational chemistry , organic chemistry , mathematics , catalysis , medicine , alternative medicine , pathology , geometry

Charge changes everything : The cationic terminal aminoborylene complex [CpFe(CO) 2 (BNCy 2 )] + [BAr F 4 ] − ( 1 , Cy= cyclohexyl, Ar F =3,5‐(CF 3 ) 2 C 6 H 3 ; Fe orange, B green, N blue, O red, C gray) was structurally characterized. DFT studies (see HOMO−2) indicate delocalized π bonding along the linear Fe‐B‐N framework and significant FeB and BN multiple‐bond character.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research