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Mechanistic Questions about the Reaction of Molecular Oxygen with Palladium in Oxidase Catalysis
Author(s) -
Gligorich Keith M.,
Sigman Matthew S.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602138
Subject(s) - catalysis , palladium , substrate (aquarium) , chemistry , molecular oxygen , oxygen , photochemistry , combinatorial chemistry , organic chemistry , biology , ecology
Which pathway? Aerobic Pd‐catalyzed oxidation reactions couple organic‐substrate oxidation to the reduction of O 2 . Two pathways are prevalent for the regeneration of the active Pd II catalyst (see scheme; SubH 2 = substrate; Sub Ox =oxidized substrate), and recent studies have provided a deeper fundamental understanding of the interactions of Pd with O 2 .
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