On Water and in Air: Fast and Highly Chemoselective Transfer Hydrogenation of Aldehydes with Iridium Catalysts | Zendy

Wu Xiaofeng | Zendy; Liu Jianke | Zendy; Li Xiaohong | Zendy; ZanottiGerosa Antonio | Zendy; Hancock Fred | Zendy; Vinci Daniele | Zendy; Ruan Jiwu | Zendy; Xiao Jianliang | Zendy

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On Water and in Air: Fast and Highly Chemoselective Transfer Hydrogenation of Aldehydes with Iridium Catalysts

Author(s) -

Wu Xiaofeng,

Liu Jianke,

Li Xiaohong,

ZanottiGerosa Antonio,

Hancock Fred,

Vinci Daniele,

Ruan Jiwu,

Xiao Jianliang

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602122

Subject(s) - iridium , transfer hydrogenation , catalysis , ethylenediamine , solvent , chemistry , combinatorial chemistry , organic chemistry , ruthenium

Water as solvent : A fast, selective, and high‐yielding transfer hydrogenation of a wide range of aldehydes is achieved using Ir III catalysts containing simple ethylenediamine (en) ligands (see scheme; Ts= p ‐toluenesulfonyl, TOF=turnover frequency). This procedure is suitable for aldehydes with a wide range of functional groups.

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