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An [Fe II 3 O] 4+ Core Wrapped by Two [Fe II L 3 ] − Units
Author(s) -
Yoneda Ko,
Adachi Keiichi,
Nishio Kyonosuke,
Yamasaki Mikio,
Fuyuhiro Akira,
Katada Motomi,
Kaizaki Sumio,
Kawata Satoshi
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602067
Subject(s) - crystallography , physics , cluster (spacecraft) , orange (colour) , content (measure theory) , ion , chemistry , computer science , mathematics , operating system , mathematical analysis , quantum mechanics , optics
An [Fe II 3 O] 4+ core in a candy wrapper : 3,5‐Bis(pyridin‐2‐yl)pyrazolate (L − ) and iron(II) ions undergo homochiral self‐assembly into a bis(triple‐helical) cluster (see picture), in which a triangular [Fe II 3 O] 4+ core (Fe orange and yellow, O red) is surrounded by two [Fe II L 3 ] − units (Fe purple, L − gray).