Premium
Structurally Characterized Quadruple‐Stranded Bisbidentate Helicates
Author(s) -
Xu Jide,
Raymond Kenneth N.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602060
Subject(s) - denticity , supramolecular chemistry , chelation , twist , crystallography , chemistry , cluster (spacecraft) , actinide , stereochemistry , crystal structure , mathematics , inorganic chemistry , computer science , geometry , programming language
Let's twist again : Actinide quadruple‐stranded helical supramolecular architectures were synthesized in which two capped square‐antiprismatic Th IV centers are coordinated by four bis(bidentate) 4‐acylpyrazolone chelating strands. This example shows a cluster formation caused by incommensurate coordination numbers.