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Bridging Rotaxanes' Wheels—Cyclochiral Bonnanes
Author(s) -
Radha Kishan Motkuri,
Parham Amir,
Schelhase Frauke,
Yoneva Albena,
Silva Gabriele,
Chen Xiaoming,
Okamoto Yoshio,
Vögtle Fritz
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602002
Subject(s) - rotaxane , bridging (networking) , enantiomer , chemistry , yield (engineering) , stereochemistry , combinatorial chemistry , supramolecular chemistry , nanotechnology , polymer science , computer science , materials science , molecule , organic chemistry , computer network , composite material
Building bridges : The wheels of [3]rotaxane were intramolecularly tethered to yield the first member of cyclochiral, interlocked architectures named “bonnanes” (after the city Bonn, Germany; see scheme). The enantiomers and meso form were separated on an immobilized chiral phase and characterized.