High H 2  Adsorption by Coordination‐Framework Materials | Zendy

Lin Xiang | Zendy; Jia Junhua | Zendy; Zhao Xuebo | Zendy; Thomas K. Mark | Zendy; Blake Alexander J. | Zendy; Walker Gavin S. | Zendy; Champness Neil R. | Zendy; Hubberstey Peter | Zendy; Schröder Martin | Zendy

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High H 2 Adsorption by Coordination‐Framework Materials

Author(s) -

Lin Xiang,

Jia Junhua,

Zhao Xuebo,

Thomas K. Mark,

Blake Alexander J.,

Walker Gavin S.,

Champness Neil R.,

Hubberstey Peter,

Schröder Martin

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200601991

Subject(s) - adsorption , carboxylate , sorption , ion , coordination number , porosity , gray (unit) , porous medium , chemistry , crystallography , chemical engineering , mineralogy , materials science , stereochemistry , organic chemistry , engineering , medicine , radiology

First‐class accommodation : A series of coordination frameworks with different pore sizes (see structure of one; Cu blue, C gray, H white, O red) are prepared from Cu II ions and carboxylate ligands of various lengths. Comparison of their sorption properties reveals that smaller pores allow higher densities of adsorbed H 2 , whereas larger pores allow higher maximum H 2 storage capacities.

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