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Zirconocene‐Catalyzed Reactions of Alkenyl‐Substituted Enol Ethers
Author(s) -
Barluenga José,
ÁlvarezRodrigo Lucía,
Rodríguez Félix,
Fañanás Francisco J.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601959
Subject(s) - enol , isomerization , catalysis , reagent , chemistry , alkene , cyclopentadienyl complex , organic chemistry , enol ether
A straightforward approach : An unprecedented zirconocene‐catalyzed isomerization–magnesation reaction of readily available alkene‐substituted enol ethers allows the direct synthesis of functionalized Grignard reagents. Cp=cyclopentadienyl.
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