Synthesis and Structure of the “Dialuminyne” Na 2 [Ar′AlAlAr′] and Na 2 [(Ar′′Al) 3 ]: AlAl Bonding in Al 2 Na 2  and Al 3 Na 2  Clusters | Zendy

Wright Robert J. | Zendy; Brynda Marcin | Zendy; Power Philip P. | Zendy

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Synthesis and Structure of the “Dialuminyne” Na 2 [Ar′AlAlAr′] and Na 2 [(Ar′′Al) 3 ]: AlAl Bonding in Al 2 Na 2 and Al 3 Na 2 Clusters

Author(s) -

Wright Robert J.,

Brynda Marcin,

Power Philip P.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200601925

Subject(s) - bent molecular geometry , planar , crystallography , bond length , physics , combinatorics , computer science , computer graphics (images) , materials science , chemistry , mathematics , crystal structure , composite material

An alkyne analogue with Al : The first “dialuminyne” of formula Na 2 [Ar′AlAlAr′] (see picture; Ar′=C 6 H 3 ‐2,6‐(C 6 H 3 ‐2,6‐ i Pr 2 ) 2 ) was synthesized and characterized by X‐ray crystallography. The structure contains a planar trans ‐bent C–Al–Al–C array with an AlAl bond length of 2.428(1) Å and a bending angle of 131.71(7)° at Al.

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