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Enantioselective Palladium‐Catalyzed Decarboxylative Allylic Alkylations
Author(s) -
You ShuLi,
Dai LiXin
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601889
Subject(s) - stereocenter , tsuji–trost reaction , palladium , enantioselective synthesis , allylic rearrangement , catalysis , chemistry , organic chemistry , combinatorial chemistry
Triple A : Recent developments in palladium‐catalyzed decarboxylative asymmetric allylic alkylation (AAA) reactions provide easy access to highly enantioenriched ketones with α‐positioned quaternary or tertiary carbon stereocenters under mild conditions.