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Multilayer Sequential Assembly of Thin Films That Display Room‐Temperature Spin Crossover with Hysteresis
Author(s) -
Cobo Saioa,
Molnár Gábor,
Real José Antonio,
Bousseksou Azzedine
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601885
Subject(s) - spin crossover , hysteresis , crossover , thin film , spin (aerodynamics) , pyrazine , thermal hysteresis , materials science , polymer , nanotechnology , condensed matter physics , crystallography , computer science , physics , chemistry , stereochemistry , thermodynamics , composite material , artificial intelligence , phase transition
Assembly time : Thin films of [Fe(pyrazine){M(CN) 4 }] (M=Ni, Pd, or Pt) coordination polymers were assembled sequentially through coordinate bonding on gold surfaces (see scheme). These multilayers exhibit spin‐crossover phenomena with hysteresis at room temperature.