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Ion‐Transfer Reactions at the Nanoscopic Water/ n ‐Octanol Interface
Author(s) -
Jing Ping,
Zhang Meiqin,
Hu Hu,
Xu Xiaodong,
Liang Zhongwei,
Li Bo,
Shen Li,
Xie Shubao,
Pereira Carlos M.,
Shao Yuanhua
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601826
Subject(s) - interface (matter) , partition (number theory) , nanoscopic scale , ion , transfer (computing) , octanol , information transfer , computer science , chemistry , chemical physics , analytical chemistry (journal) , partition coefficient , nanotechnology , physics , materials science , environmental chemistry , organic chemistry , mathematics , combinatorics , telecommunications , parallel computing , adsorption , gibbs isotherm
Sharp practice : A water/ n ‐octanol interface can be formed at the tip of a very short and sharp nanopipette, and can be polarized externally (see picture). This interface has been used to investigate various ion‐transfer processes and evaluate partition coefficients for ionizable species.