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Mono‐ and Dimetalated Ferrocenylcopper Complexes by Tin–Copper Exchange
Author(s) -
Venkatasubbaiah Krishnan,
DiPasquale Antonio G.,
Bolte Michael,
Rheingold Arnold L.,
Jäkle Frieder
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601820
Subject(s) - tin , ferrocene , atom (system on chip) , transition metal , copper , chemistry , aggregate (composite) , metal , content (measure theory) , computer science , crystallography , nanotechnology , combinatorial chemistry , materials science , mathematics , organic chemistry , catalysis , electrode , electrochemistry , embedded system , mathematical analysis
Fe binds simultaneously : Reaction of 1,2‐fc(SnMe 3 ) 2 (fc=(C 5 H 5 )Fe(C 5 H 3 )) with [C 6 F 5 Cu] 4 selectively leads to the multimetallic aggregate [(1,2‐fcCu 2 ) 4 (C 6 F 5 Cu) 8 ] (see picture), which offers rare insight into the structural complexity of highly aggregated arylenedicopper species and provides the first evidence that the central iron atom in ferrocene can interact simultaneously with multiple Lewis acidic transition‐metal centers.