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Hypervalent Iodine Goes Catalytic
Author(s) -
Richardson Robert D.,
Wirth Thomas
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601817
Subject(s) - hypervalent molecule , iodine , catalysis , reagent , chemistry , phenol , stoichiometry , organic chemistry , combinatorial chemistry
A dash of iodine : Different reactions relying on the power of hypervalent iodine reagents can now be performed with catalytic amounts of these compounds and a stoichiometric oxidant. Oxidations of alcohols, α‐functionalizations of ketones, and spirocyclizations of phenol derivatives are possible.