Premium
A Square‐Planar Organoiron(III) Compound with a Spin‐Admixed State
Author(s) -
Alonso Pablo J.,
Arauzo Ana B.,
Forniés Juan,
GarcíaMonforte M. Angeles,
Martín Antonio,
Martínez Jesús I.,
Menjón Babil,
Rillo Conrado,
SáizGaritaonandia José J.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601774
Subject(s) - homoleptic , planar , square (algebra) , crystallography , spin states , ion , chemistry , stereochemistry , computer science , organic chemistry , inorganic chemistry , mathematics , geometry , computer graphics (images) , metal
Square‐planar iron(III) species bearing no axial ligands can still behave as spin‐admixed systems ( S =3/2, 5/2). The highly unusual homoleptic σ‐organoiron complex [Li(thf) 4 ][Fe III (C 6 Cl 5 ) 4 ] (see anion in picture; green Cl, gray C) is an example of such a system.