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Highly Selective 1,6‐Addition of Aryl Boronic Acids to α,β,γ,δ‐Unsaturated Carbonyl Compounds Catalyzed by an Iridium Complex
Author(s) -
Nishimura Takahiro,
Yasuhara Yuichi,
Hayashi Tamio
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601719
Subject(s) - iridium , aryl , catalysis , chemistry , combinatorial chemistry , selectivity , organic chemistry , alkyl
Perfect control : The catalytic 1,6‐addition of aryl boronic acids to electron‐deficient dienes was realized by use of an iridium catalyst (see scheme). High yields of the corresponding δ‐arylated carbonyl compounds were obtained with perfect 1,6‐selectivity.