The First Structural Characterization of a Binary P–N Molecule: The Highly Energetic Compound P 3 N 21 | Zendy

Göbel Michael | Zendy; Karaghiosoff Konstantin | Zendy; Klapötke Thomas M. | Zendy

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The First Structural Characterization of a Binary P–N Molecule: The Highly Energetic Compound P 3 N 21

Author(s) -

Göbel Michael,

Karaghiosoff Konstantin,

Klapötke Thomas M.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200601670

Subject(s) - molecule , binary number , characterization (materials science) , diffraction , phosphorus , nitrogen , orange (colour) , crystallography , explosive material , azide , chemistry , crystal structure , materials science , nanotechnology , physics , organic chemistry , mathematics , arithmetic , optics , food science

An explosive mixture : The first structural characterization of a binary molecule of phosphorus and nitrogen is described. With the help of a new synthetic strategy, the phosphorus azide P 3 N 21 is prepared in pure form, and single crystals are isolated, enabling a structure determination by X‐ray diffraction (see structure; P orange, N blue).

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