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Sandwich Complexes Containing Bent Palladium Chains
Author(s) -
Tatsumi Yasuki,
Shirato Katsunori,
Murahashi Tetsuro,
Ogoshi Sensuke,
Kurosawa Hideo
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601641
Subject(s) - bent molecular geometry , palladium , chain (unit) , crystallography , conjugated system , orange (colour) , arch , materials science , chemistry , polymer , physics , composite material , structural engineering , optics , catalysis , engineering , organic chemistry , astronomy
Hold the mayo! Sandwich complexes containing the arch‐shaped Pd 4 chain (upper structure; C blue, Pd orange) or the V‐shaped Pd 5 chain (lower) were synthesized and structurally characterized. The bending angles of the Pd chains reflect the p π‐conjugated geometry of the template ligands.