Porous Cobalt(II)–Organic Frameworks with Corrugated Walls: Structurally Robust Gas‐Sorption Materials | Zendy

Humphrey Simon M. | Zendy; Chang JongSan | Zendy; Jhung Sung Hwa | Zendy; Yoon Ji Woong | Zendy; Wood Paul T. | Zendy

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Porous Cobalt(II)–Organic Frameworks with Corrugated Walls: Structurally Robust Gas‐Sorption Materials

Author(s) -

Humphrey Simon M.,

Chang JongSan,

Jhung Sung Hwa,

Yoon Ji Woong,

Wood Paul T.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200601627

Subject(s) - sorption , porosity , adsorption , cobalt , chemical engineering , chemistry , materials science , crystallography , inorganic chemistry , organic chemistry , engineering

Resilient hosts : The porous coordination solids CUK‐1 (see structure; Co purple, C gray, N blue, O red/pink) and CUK‐2 are synthesized from unsymmetrical ligands and Co II ions. Even after the removal of co‐crystallized guests, the host frameworks are exceptionally stable. CUK‐1 shows a high capacity for H 2 adsorption and is one of very few materials capable of separating N 2 from O 2 .

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