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Supramolecular Assemblies of Chiral Propargylic Alcohols
Author(s) -
Hyacinth Marilise,
Chruszcz Maksymilian,
Lee Ki Sung,
Sabat Michal,
Gao Ge,
Pu Lin
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601594
Subject(s) - supramolecular chemistry , enantiomer , chemistry , supramolecular assembly , molecule , solvent , solid state , stereochemistry , combinatorial chemistry , nanotechnology , organic chemistry , materials science
Six pack : A hexameric supramolecular structure with alternating enantiomers is formed in the solid state from propargylic alcohols. These hexamers further assemble to form channels and cages that host solvent molecules. The synergistic cooperation of OH⋅⋅⋅O, CH⋅⋅⋅FC, and π–π interactions is important in establishing the supramolecular assembly.