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Formation of an Organometallic Ladderane Derivative by Dynamic Topochemical Reaction Control
Author(s) -
Paradies Jan,
Greger Ingo,
Kehr Gerald,
Erker Gerhard,
Bergander Klaus,
Fröhlich Roland
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601592
Subject(s) - derivative (finance) , photodissociation , chemistry , group 2 organometallic chemistry , organometallic chemistry , computational chemistry , stereochemistry , organic chemistry , molecule , catalysis , financial economics , economics
Coming together at the ends : Bis(butadienylcyclopentadienyl) dichlorozirconium ( 1 ) undergoes dynamic topochemical reactions upon photolysis that eventually lead to the formation of ladderane derivative 2 and the organometallic cyclooctadiene derivative 3 .