Substituted Allyl Diphenylphosphine Oxides as Radical Allylating Agents | Zendy

Ouvry Gilles | Zendy; QuicletSire Béatrice | Zendy; Zard Samir Z. | Zendy

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Substituted Allyl Diphenylphosphine Oxides as Radical Allylating Agents

Author(s) -

Ouvry Gilles,

QuicletSire Béatrice,

Zard Samir Z.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200601556

Subject(s) - diphenylphosphine , diphenylphosphine oxide , reagent , chemistry , content (measure theory) , scheme (mathematics) , medicinal chemistry , combinatorial chemistry , organic chemistry , phosphine , catalysis , mathematics , mathematical analysis

Radically useful : The radical addition of dithiocarbonates to branched allyl diphenylphosphine oxides can be followed by elimination of a diphenylphosphinoyl radical, thereby giving rise to allylated products (see scheme; Phth=phthalimido). Highly functionalized structures can thus be rapidly assembled under mild conditions and from cheap and readily available substrates and reagents.

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