Synthesis and Redox Properties of Mixed‐Valent Octanuclear Iron Defective Hexacubanes and a (CaCl)‐Capped Body‐Centered Six‐Sided Iron(III) Polyhedron | Zendy

Prakash Raju | Zendy; Saalfrank Rolf W. | Zendy; Maid Harald | Zendy; Scheurer Andreas | Zendy; Heinemann Frank W. | Zendy; Trautwein Alfred X. | Zendy; Böttger Lars H. | Zendy

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Synthesis and Redox Properties of Mixed‐Valent Octanuclear Iron Defective Hexacubanes and a (CaCl)‐Capped Body‐Centered Six‐Sided Iron(III) Polyhedron

Author(s) -

Prakash Raju,

Saalfrank Rolf W.,

Maid Harald,

Scheurer Andreas,

Heinemann Frank W.,

Trautwein Alfred X.,

Böttger Lars H.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200601478

Subject(s) - polyhedron , diethanolamine , redox , chemistry , crystallography , ion , inorganic chemistry , combinatorics , mathematics , organic chemistry

Available in assorted shapes : Three new oligonuclear complexes self‐assemble from t Bu‐ N ‐diethanolamine and mixtures of iron(II) and iron(III) ions. Depending on the reaction conditions, a compact or linear defective hexacubane, or a body‐centered six‐sided iron(III) polyhedron (see structure; Fe gold, Ca purple, C gray, N blue, O red, Cl green) is formed.

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