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Synthesis and Redox Properties of Mixed‐Valent Octanuclear Iron Defective Hexacubanes and a (CaCl)‐Capped Body‐Centered Six‐Sided Iron(III) Polyhedron
Author(s) -
Prakash Raju,
Saalfrank Rolf W.,
Maid Harald,
Scheurer Andreas,
Heinemann Frank W.,
Trautwein Alfred X.,
Böttger Lars H.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601478
Subject(s) - polyhedron , diethanolamine , redox , chemistry , crystallography , ion , inorganic chemistry , combinatorics , mathematics , organic chemistry
Available in assorted shapes : Three new oligonuclear complexes self‐assemble from t Bu‐ N ‐diethanolamine and mixtures of iron(II) and iron(III) ions. Depending on the reaction conditions, a compact or linear defective hexacubane, or a body‐centered six‐sided iron(III) polyhedron (see structure; Fe gold, Ca purple, C gray, N blue, O red, Cl green) is formed.