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Efficient Synthesis of Functionalized Organozinc Compounds by the Direct Insertion of Zinc into Organic Iodides and Bromides
Author(s) -
Krasovskiy Arkady,
Malakhov Vladimir,
Gavryushin Andrei,
Knochel Paul
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601450
Subject(s) - zinc , reagent , chemistry , insider , combinatorial chemistry , insertion reaction , organic synthesis , organic chemistry , catalysis , law , political science
Insider dealing : A wide range of polyfunctional (hetero)aromatic and aliphatic zinc reagents can be easily prepared in THF. The compounds are formed by a Zn insertion reaction mediated by the addition of LiCl (see scheme; All=allyl).
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