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Iron and Manganese Corroles Are Potent Catalysts for the Decomposition of Peroxynitrite
Author(s) -
Mahammed Atif,
Gross Zeev
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601399
Subject(s) - manganese , peroxynitrite , catalysis , disproportionation , decomposition , chemistry , catalytic cycle , inorganic chemistry , photochemistry , organic chemistry , superoxide , enzyme
Ring cycle : Iron and manganese corroles are among the most efficient decomposition catalysts of peroxynitrite reported to date. The catalytic rate of the iron complex is higher than that of analogous porphyrins, and the manganese complex operates through the catalytic disproportionation cycle shown in the picture.