Trigonal Pyramids: Alternative Ground‐State Structures for Sixteen‐Electron Complexes | Zendy

Ostendorf Detlev | Zendy; Landis Clark | Zendy; Grützmacher Hansjörg | Zendy

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Trigonal Pyramids: Alternative Ground‐State Structures for Sixteen‐Electron Complexes

Author(s) -

Ostendorf Detlev,

Landis Clark,

Grützmacher Hansjörg

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200601352

Subject(s) - trigonal crystal system , rhodium , trigonal pyramidal molecular geometry , chemistry , crystallography , olefin fiber , ligand (biochemistry) , ground state , silylation , stereochemistry , crystal structure , physics , organic chemistry , atomic physics , catalysis , receptor , biochemistry

A structural alternative for sixteen‐electron ML 4 complexes is the trigonal‐pyramidal (TP) form. This has been demonstrated by the preparation of TP complexes of rhodium(I) with three equatorial olefin ligands and one axial silyl ligand (see picture: C black, Rh blue, Si orange).

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