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Radical‐Mediated Alkenylation, Alkynylation, Methanimination, and Cyanation of B ‐Alkylcatecholboranes
Author(s) -
Schaffner ArnaudPierre,
Darmency Vincent,
Renaud Philippe
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601206
Radical connection : Organoboranes, prepared in situ from hydroboration of olefins with catecholborane, undergo efficient coupling reactions with vinyl and alkynyl sulfones through a radical mechanism. This procedure was also extended to the acylation and cyanation of organoboranes.