A Conjugated Polycarbazole Ring around a Porphyrin | Zendy

Jung SungHyun | Zendy; Pisula Wojciech | Zendy; Rouhanipour Ali | Zendy; Räder Hans Joachim | Zendy; Jacob Josemon | Zendy; Müllen Klaus | Zendy

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A Conjugated Polycarbazole Ring around a Porphyrin

Author(s) -

Jung SungHyun,

Pisula Wojciech,

Rouhanipour Ali,

Räder Hans Joachim,

Jacob Josemon,

Müllen Klaus

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200601131

Subject(s) - porphyrin , conjugated system , carbazole , ring (chemistry) , hexagonal crystal system , core (optical fiber) , molecule , nanotechnology , materials science , crystallography , chemistry , photochemistry , physics , optics , polymer , organic chemistry

Round up : A fully conjugated cyclododeca‐2,7‐carbazole is prepared around a porphyrin template and the corresponding empty macrocycle then released. Single molecules could be visualized by STM (see image) and their arrangement by atomic force microscopy. The macrocycles self‐assemble into a hexagonal array of columns. Efficient energy transfer occurs from the peripheral carbazole π system to the central porphyrin core.

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