Premium
[Rb([18]crown‐6)(NH 3 ) 3 ]Au⋅NH 3 : Gold as Acceptor in NH⋅⋅⋅Au − Hydrogen Bonds
Author(s) -
Nuss Hanne,
Jansen Martin
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601093
Subject(s) - acceptor , hydrogen bond , chemistry , ion , crystallography , orange (colour) , molecule , physics , organic chemistry , food science , condensed matter physics
Golden bridge : In the title complex, the auride anion acts as an acceptor in NH⋅⋅⋅Au − hydrogen bonds (see molecular structure; C gray, H white, N blue, O red, Au orange, Rb violet). For the first time, experimental values for an H⋅⋅⋅Au − distance and the corresponding N‐H‐Au angle could be determined.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom