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[Rb([18]crown‐6)(NH 3 ) 3 ]Au⋅NH 3 : Gold as Acceptor in NH⋅⋅⋅Au − Hydrogen Bonds
Author(s) -
Nuss Hanne,
Jansen Martin
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601093
Subject(s) - acceptor , hydrogen bond , chemistry , ion , crystallography , orange (colour) , molecule , physics , organic chemistry , food science , condensed matter physics
Golden bridge : In the title complex, the auride anion acts as an acceptor in NH⋅⋅⋅Au − hydrogen bonds (see molecular structure; C gray, H white, N blue, O red, Au orange, Rb violet). For the first time, experimental values for an H⋅⋅⋅Au − distance and the corresponding N‐H‐Au angle could be determined.