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“Click” Chemistry by Microcontact Printing
Author(s) -
Rozkiewicz Dorota I.,
Jańczewski Dominik,
Verboom Willem,
Ravoo Bart Jan,
Reinhoudt David N.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601090
Subject(s) - microcontact printing , click chemistry , substrate (aquarium) , nanotechnology , monolayer , computer science , nanoscopic scale , silicon , chemistry , materials science , combinatorial chemistry , optoelectronics , oceanography , geology
Print and click : “Click” chemistry can be efficiently combined with microcontact printing. Synthesis in the nanoscale confinement between an elastomeric stamp and a reactive substrate leads to the desired product within a short time, without a catalyst, and under ambient conditions. As a result, 1‐octadecyne could be printed onto an azido‐terminated, self‐assembled monolayer on a silicon oxide substrate (see scheme).