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Preparation, Characterization, and Crystal Structures of the SO 3 NHF − and SO 3 NF 2 − Ions
Author(s) -
Haiges Ralf,
Wagner Ross,
Boatz Jerry A.,
Yousufuddin Muhammed,
Etzkorn Markus,
Prakash G. K. Surya,
Christe Karl O.,
Chapman Robert D.,
Welker Mark F.,
Kreutzberger Charles B.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200601020
Subject(s) - reagent , ion , characterization (materials science) , aqueous solution , chemistry , inorganic chemistry , crystal (programming language) , radiochemistry , crystallography , nuclear chemistry , materials science , nanotechnology , organic chemistry , computer science , programming language
Safe difluoroaminating reagents : Salts of the elusive SO 3 NF 2 − ion were prepared by aqueous fluorination of SO 3 NH 2 − with F 2 . These salts were characterized (see ORTEP of the anion) and shown to be excellent reagents for the preparation of gem ‐bis(difluoroamines). Salts of the intermediate SO 3 NHF − ion were also isolated and characterized.