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Guest‐Induced Instant and Reversible Crystal‐to‐Crystal Transformation of 1,4‐Bis(ferrocenylethynyl)anthraquinone
Author(s) -
Kondo Mio,
Murata Masaki,
Nishihara Hiroshi,
Nishibori Eiji,
Aoyagi Shinobu,
Yoshida Masanori,
Kinoshita Yusuke,
Sakata Makoto
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200600933
Subject(s) - anthraquinone , instant , crystal (programming language) , transformation (genetics) , chemistry , materials science , crystallography , photochemistry , organic chemistry , computer science , food science , programming language , biochemistry , gene
Both porous and nonporous structures are formed by crystals of donor–acceptor (D–A) compound 1,4‐bis(ferrocenylethynyl)anthraquinone. The guest‐incorporating porous and guest‐free nonporous structures can interchange instantly and reversibly by desorption and adsorption of guest molecules, which cause alternation of D–A and D–A–A arrangements in the one‐dimensional columnar structure (see picture).