Solid‐State Phase Transition of an Inclusion Complex of 5‐Methyl‐2‐pyridone with 1,3,5‐Benzenetricarboxylic Acid | Zendy

Hirano Shinya | Zendy; Toyota Shinji | Zendy; Toda Fumio | Zendy; Fujii Kotaro | Zendy; Uekuasa Hidehiro | Zendy

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Solid‐State Phase Transition of an Inclusion Complex of 5‐Methyl‐2‐pyridone with 1,3,5‐Benzenetricarboxylic Acid

Author(s) -

Hirano Shinya,

Toyota Shinji,

Toda Fumio,

Fujii Kotaro,

Uekuasa Hidehiro

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200600845

Subject(s) - trimesic acid , chemistry , solvent , molecule , inclusion (mineral) , flash (photography) , phase (matter) , phase transition , solid state , organic chemistry , thermodynamics , mineralogy , physics , art , visual arts

Changed in a flash : A photochemically unreactive crystal of 5‐methyl‐2‐pyridone with a trimesic acid host is transformed in the solid state into a reactive phase by heating or by contact with solvent vapor. The mechanism was revealed to involve desolvation and a 180° turn of one molecule with respect to the other.

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