Premium
Regio‐ and Enantioselective Epoxidation of Dienes by a Chiral Dioxirane: Synthesis of Optically Active Vinyl cis ‐Epoxides
Author(s) -
Burke Christopher P.,
Shi Yian
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200600840
Subject(s) - enantioselective synthesis , dioxirane , organic chemistry , chemistry , catalysis , ketone , conjugated system , epoxide , optically active , polymer
Putting the O into olefins : A highly regio‐ and enantioselective epoxidation of conjugated dienes was developed using glucose‐derived ketone 1 as catalyst and oxone (KHSO 5 ) as oxidant to form vinyl cis ‐epoxides (see scheme).
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom