Chiral Borromeates | Zendy

Pentecost Cari D. | Zendy; Peters Andrea J. | Zendy; Chichak Kelly S. | Zendy; Cave Gareth W. V. | Zendy; Cantrill Stuart J. | Zendy; Stoddart J. Fraser | Zendy

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Chiral Borromeates

Author(s) -

Pentecost Cari D.,

Peters Andrea J.,

Chichak Kelly S.,

Cave Gareth W. V.,

Cantrill Stuart J.,

Stoddart J. Fraser

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200600817

Subject(s) - stereocenter , chirality (physics) , circular dichroism , enantiomer , crystallography , octahedron , solid state , stereochemistry , chemistry , physics , enantioselective synthesis , crystal structure , organic chemistry , chiral symmetry , catalysis , quantum mechanics , quark , nambu–jona lasinio model

The fellowship of the rings : Circular dichroism measurements reveal that chirality is transferred from 12 stereogenic centers to 6 octahedral zinc(II) centers (see picture) in two enantiomeric pairs of chiral Borromeates, one of which has been found to be wholly asymmetric in the solid state by X‐ray crystallography.

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