Transition‐Metal‐Free Homocoupling of Organomagnesium Compounds | Zendy

Krasovskiy Arkady | Zendy; Tishkov Alexander | Zendy; del Amo Vicente | Zendy; Mayr Herbert | Zendy; Knochel Paul | Zendy

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Transition‐Metal‐Free Homocoupling of Organomagnesium Compounds

Author(s) -

Krasovskiy Arkady,

Tishkov Alexander,

del Amo Vicente,

Mayr Herbert,

Knochel Paul

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200600772

Subject(s) - palladium , reagent , transition metal , chemistry , acceptor , copper , grignard reagent , group 2 organometallic chemistry , combinatorial chemistry , electron acceptor , metal , oxidative addition , polymer chemistry , organic chemistry , molecule , catalysis , physics , condensed matter physics

Without palladium or copper : A wide range of functionalized Grignard compounds were coupled by using diphenoquinone 1 as an electron acceptor. The oxidative dimerization of alkenylmagnesium reagents proceeds with complete retention of the stereochemistry (see scheme; TBDMS= tert ‐butyldimethylsilyl).

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