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Cationic Terminal Borylene Complexes: Interconversion of Amino and Alkoxy Borylenes by an Unprecedented Meerwein–Ponndorf Hydride Transfer
Author(s) -
Kays née Coombs Deborah L.,
Day Joanna K.,
Aldridge Simon,
Harrington Ross W.,
Clegg William
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200600714
Subject(s) - chemistry , benzophenone , hydride , cationic polymerization , ketone , ligand (biochemistry) , stereochemistry , combinatorial chemistry , photochemistry , organic chemistry , biochemistry , receptor , hydrogen
It's all new to B : In the reaction of borylene complex 1 with benzophenone, a Meerwein–Ponndorf β‐hydride transfer from the aminoborylene ligand to the coordinated ketone generates 2 (see structure), the first example of an imine‐donor‐stabilized borylene complex, and the first cationic alkoxyborylene system.