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Interstrand Interactions between Side Chains in a Double‐Helical Foldamer
Author(s) -
Haldar Debasish,
Jiang Hua,
Léger JeanMichel,
Huc Ivan
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200600698
Subject(s) - foldamer , side chain , oligomer , stereochemistry , duplex (building) , helix (gastropod) , chemistry , pyridine , molecule , solid state , crystallography , computer science , organic chemistry , biochemistry , biology , polymer , dna , ecology , snail
Hairy molecules! The numerous benzyloxy side chains sticking out of a helically folded pyridine carboxamide oligomer bring about considerable stabilization to its double‐helical conformation. The structure of the duplex was studied both in solution and in the solid state.