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Lithiation/Electrophilic Quench of [(η 5 ‐Cyclohexadienyl)Mn(CO) 3 ]: Versatile Functionalization and Resolution of Planar Chirality in the Organomanganese Series
Author(s) -
Jacques Béatrice,
Chavarot Murielle,
RoseMunch Françoise,
Rose Eric
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200600689
Subject(s) - enantiopure drug , electrophile , chirality (physics) , chemistry , surface modification , combinatorial chemistry , computational chemistry , enantioselective synthesis , organic chemistry , physics , catalysis , particle physics , quark , nambu–jona lasinio model , chiral symmetry breaking
Easy does it : A lithiation/electrophilic quench sequence gives efficient access to a large variety of unprecedented complexes. One such complex ( 1 ; see scheme) can be successfully used in the synthesis of the first enantiopure formyl‐substituted [(η 5 ‐cyclohexadienyl)Mn(CO) 3 ] derivatives.