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Thermal Production and Reactions of Organic Ions at Atmospheric Pressure
Author(s) -
Chen Hao,
Ouyang Zheng,
Cooks R. Graham
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200600660
Subject(s) - derivatization , ion , atmospheric pressure , chemistry , ionization , desorption , thermal desorption , thermal , ionic bonding , inorganic chemistry , atmospheric pressure chemical ionization , molecule , ionic liquid , photochemistry , analytical chemistry (journal) , mass spectrometry , chemical ionization , organic chemistry , chromatography , thermodynamics , adsorption , catalysis , oceanography , physics , geology
The heat is on : Thermal ionization of a variety of organic salts including ionic liquids and transition‐metal salts occurs at atmospheric pressure. This thermal method allows for the study of ion–molecule reactions; for example, the fast selective desorption and derivatization of D ‐lysine occurs when thermally generated pyrylium ions react with solid lysine under ambient conditions (see picture).