Topochemical Polymerization in Supramolecular Polymers of Oligopeptide‐Functionalized Diacetylenes | Zendy

Jahnke Eike | Zendy; Lieberwirth Ingo | Zendy; Severin Nikolai | Zendy; Rabe Jürgen P. | Zendy; Frauenrath Holger | Zendy

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Topochemical Polymerization in Supramolecular Polymers of Oligopeptide‐Functionalized Diacetylenes

Author(s) -

Jahnke Eike,

Lieberwirth Ingo,

Severin Nikolai,

Rabe Jürgen P.,

Frauenrath Holger

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200600610

Subject(s) - diacetylene , supramolecular chemistry , polymerization , polymer , copolymer , polymer science , polymer chemistry , chemistry , materials science , nanotechnology , organic chemistry , molecule

Diacetylene macromonomers functionalized with a β‐sheet‐forming oligopeptide and a hydrogenated poly(isoprene) coil segment self‐assembled into supramolecular polymers with a double‐helical, tubular topology and a diameter of a few nanometers. Subsequent “1D topochemical polymerization” affords poly(diacetylene)s with a conjugated backbone and a high degree of biochemically relevant functionalization, as well as a defined hierarchical structure.

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