A Supramolecular Photocatalyst for the Production of Hydrogen and the Selective Hydrogenation of Tolane | Zendy

Rau Sven | Zendy; Schäfer Bernhard | Zendy; Gleich Dieter | Zendy; Anders Ernst | Zendy; Rudolph Manfred | Zendy; Friedrich Manfred | Zendy; Görls Helmar | Zendy; Henry William | Zendy; Vos Johannes G. | Zendy

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A Supramolecular Photocatalyst for the Production of Hydrogen and the Selective Hydrogenation of Tolane

Author(s) -

Rau Sven,

Schäfer Bernhard,

Gleich Dieter,

Anders Ernst,

Rudolph Manfred,

Friedrich Manfred,

Görls Helmar,

Henry William,

Vos Johannes G.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200600543

Subject(s) - photocatalysis , intramolecular force , supramolecular chemistry , catalysis , bridging ligand , chemistry , hydrogen production , relay , redox , combinatorial chemistry , photochemistry , organic chemistry , molecule , physics , power (physics) , quantum mechanics

Light‐driven metallo‐organic catalysis: Intramolecular photoelectron transfer in the heterodinuclear complex 1 facilitates the photocatalytic production of hydrogen and the selective hydrogenation of tolane to give cis ‐stilbene. All three well‐coordinated parts of the supramolecular system are essential: the (tbbpy) 2 Ru fragment as a photoactive unit, the redox‐active bridging ligand as an electron relay and storage site, and the palladium as a catalytically active center.

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