Single‐Step Conversion of Dimethyl Terephthalate into Cyclohexanedimethanol with Ru 5 PtSn, a Trimetallic Nanoparticle Catalyst | Zendy

Hungria Ana B. | Zendy; Raja Robert | Zendy; Adams Richard D. | Zendy; Captain Burjor | Zendy; Thomas John Meurig | Zendy; Midgley Paul A. | Zendy; Golovko Vladimir | Zendy; Johnson Brian F. G. | Zendy

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Single‐Step Conversion of Dimethyl Terephthalate into Cyclohexanedimethanol with Ru 5 PtSn, a Trimetallic Nanoparticle Catalyst

Author(s) -

Hungria Ana B.,

Raja Robert,

Adams Richard D.,

Captain Burjor,

Thomas John Meurig,

Midgley Paul A.,

Golovko Vladimir,

Johnson Brian F. G.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200600359

Subject(s) - dimethyl terephthalate , catalysis , materials science , nanoparticle , nanotechnology , chemistry , organic chemistry

Highly active and selective : A supported Ru 5 PtSn nanoparticle cluster (the picture shows an axial projection of a tomogram), prepared from the carbonyl cluster [PtRu 5 (CO) 15 (μ‐SnPh 2 )(μ 6 ‐C)], is an excellent catalyst in the single‐step hydrogenation of dimethyl terephthalate to cyclohexanedimethanol under mild conditions (100 °C, 20 bar H 2 ).

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