[{( t Bu 2 Me) 2 Si} 3 Li 4 ] 2− : An Aggregated Dianion of a 1,1‐Dilithiosilane with a Unique Structural Motif | Zendy

BravoZhivotovskii Dmitry | Zendy; Ruderfer Ilya | Zendy; Melamed Semyon | Zendy; Botoshansky Mark | Zendy; Schmidt Asher | Zendy; Apeloig Yitzhak | Zendy

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[{( t Bu 2 Me) 2 Si} 3 Li 4 ] 2− : An Aggregated Dianion of a 1,1‐Dilithiosilane with a Unique Structural Motif

Author(s) -

BravoZhivotovskii Dmitry,

Ruderfer Ilya,

Melamed Semyon,

Botoshansky Mark,

Schmidt Asher,

Apeloig Yitzhak

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200600308

Subject(s) - dilithium , content (measure theory) , dissolution , nuclear magnetic resonance spectroscopy , chemistry , solid state , salt (chemistry) , crystallography , spectroscopy , physics , stereochemistry , organic chemistry , mathematics , quantum mechanics , mathematical analysis , ion , deprotonation

An anionic dilithium compound : The dianion [(R 2 Si) 3 Li 4 ] 2− (R= t Bu 2 MeSi) as salt 2 was synthesized as the first of its kind by dissolving 1 in THF. The structure of 2 was solved by X‐ray crystallography and studied by solid‐state and solution NMR spectroscopy. Compound 2 reacts as a dilithiosilane.

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