A Hybrid Water–Chloride Structure with Discrete Undecameric Water Moieties Self‐Assembled in a Heptaprotonated Octaamino Cryptand | Zendy

Lakshminarayanan P. S. | Zendy; Suresh Eringathodi | Zendy; Ghosh Pradyut | Zendy

Premium

A Hybrid Water–Chloride Structure with Discrete Undecameric Water Moieties Self‐Assembled in a Heptaprotonated Octaamino Cryptand

Author(s) -

Lakshminarayanan P. S.,

Suresh Eringathodi,

Ghosh Pradyut

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200600254

Subject(s) - cryptand , chloride , moiety , chemistry , crystallography , chemical engineering , stereochemistry , organic chemistry , engineering , ion

Odd water clusters : An unprecedented propeller‐shaped undecameric water motif is stabilized within the lattice of the heptahydrochloride of a homoditopic octaamino cryptand with C 3 symmetry. The discrete water clusters are oriented symmetrically around the cryptand moiety and interact with encapsulated chloride inside the cavity (see structure; Cl green, O red, N blue).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research